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新型手性基团修饰的金属卟啉的合成及性质研究
引用本文:王树军,章应辉,阮文娟,罗代兵,朱志昂,田建国,刘智波.新型手性基团修饰的金属卟啉的合成及性质研究[J].物理化学学报,2006,22(8):981-986.
作者姓名:王树军  章应辉  阮文娟  罗代兵  朱志昂  田建国  刘智波
作者单位:College of Chemistry and Material Science, Langfang Teachers College, Langfang 065001, P. R. China; Department of Chemistry, Nankai University, Tianjin 300071, P. R. China;3.Applied Physics School of Teda, Nankai University, Tianjin 300071, P. R. China
基金项目:国家自然科学基金;教育部重点实验室基金;廊坊师范学院校科研和教改项目
摘    要:合成了一种手性基团修饰的金属卟啉化合物5-对(L-亮氨酰氧乙氧基)苯基-10, 15, 20-三苯基卟啉锌]. 通过元素分析、紫外可见光谱、红外光谱、圆二色光谱及核磁共振波谱对该化合物进行了较详细的表征. 同时, 采用分子力学方法搜索了主体的最低能量构象, 从理论上进一步解释实验结果. 利用Z扫描技术测定了该化合物的三阶非线性光学性质.

关 键 词:手性金属卟啉  圆二色光谱  理论计算  非线性光学性质  
收稿时间:2006-01-16
修稿时间:2006-04-04

Studies on the Synthesis and Characterization of a Novel Chiral Metalloporphyrin
WANG,Shu-Jun,ZHANG,Ying-Hui,RUAN,Wen-Juan,LUO,Dai-Bing,ZHU,Zhi-Ang,TIAN,Jian-Guo,LIU,Zhi-Bo.Studies on the Synthesis and Characterization of a Novel Chiral Metalloporphyrin[J].Acta Physico-Chimica Sinica,2006,22(8):981-986.
Authors:WANG  Shu-Jun  ZHANG  Ying-Hui  RUAN  Wen-Juan  LUO  Dai-Bing  ZHU  Zhi-Ang  TIAN  Jian-Guo  LIU  Zhi-Bo
Institution:College of Chemistry and Material Science, Langfang Teachers College, Langfang 065001, P. R. China; Department of Chemistry, Nankai University, Tianjin 300071, P. R. China;3.Applied Physics School of Teda, Nankai University, Tianjin 300071, P. R. China
Abstract:One kind of novel chiral Zn porphyrin was synthesized. By means of elementary analysis, UV-Vis, IR, CD spectrum, and 1H-NMR, the chiral Zn porphyrin was charactered. The lowest energy conformation of the chiral zinc porphyrin was obtained by system search on the basis of Tripos force field. Nonlinear optical properties of the chiral porphyrin complexes were studied and refractive indexes were measured by Z-scan techniques. The result indicates that chiral zinc porphyrin has biggish nonlinear refractive index. This is an effective method by modifying chiral structure of porphyrin complexes to increase nonlinear refractive index.
Keywords:Chiral metalloporphyrin  CD spectrum  Theoretical calculation  Nonlinear optical properties
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