| O(3P)原子与丁酮反应速率常数的测定 |
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| 引用本文： | 陈从香,刘新,高建谧,孔繁敖.O(3P)原子与丁酮反应速率常数的测定[J].物理化学学报,1988,4(5):535-538. |
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| 作者姓名： | 陈从香 刘新 高建谧 孔繁敖 |
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| 作者单位： | Department of Modern Chemistry; University of Science andTechnology of China; Hefei; Anhui |
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| 摘 要： |
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| 收稿时间： | 1987-01-22 |
| 修稿时间： | 1987-10-27 |
THE MEASUREMENT OF THE RATE CONSTANT OF REACTION BETWEEN O(3P) AND N-BUTANONE |
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| Chen Congxiang,Liu Xin,Gao Jianmi,Kong Fanao.THE MEASUREMENT OF THE RATE CONSTANT OF REACTION BETWEEN O(3P) AND N-BUTANONE[J].Acta Physico-Chimica Sinica,1988,4(5):535-538. |
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| Authors: | Chen Congxiang Liu Xin Gao Jianmi Kong Fanao |
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| Institution: | Department of Modern Chemistry; University of Science andTechnology of China; Hefei; Anhui |
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| Abstract: | The measurement of the kinetic rate constant of the reaction of O(~3P) atoms with n-butanone at 288K is carried out. O(~3P) atoms were generated by a microwave discharge flow system and the residual concentration was detected by NO_2* chemiluminescence. The specific rate constant obtained is κ=(6.2±1.2)×10~(-15)cm~3 molecule~(-1) s~(-1) (T=288 K).A correlation diagram of molecular orbitals for the reaction is discussed. |
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