Diffusion-controlled recombination of peroxide radicals in polyatomic esters |
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| Authors: | S L Khursan V S Martemianov and R L Safiullin |
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| Institution: | (1) State University, 450074 Ufa, USSR;(2) Institute of Chemistry, 450054 Ufa, USSR |
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| Abstract: | Pulse photolysis measurements of rate constants for the decay of peroxide radicals of seven polyatomic esters show that the reaction is diffusion-controlled for esters with   2 cP. The Smoluchowsky equation is suggested to calculate 2kt for esters with short alkyl radicals.
                         .  ,    - ,    2 . 2kt  .
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