Mechanism of methoxycarbonylation of 1,5-naphthalene diamino with dimethyl carbonate to 1,5-naphthalene dicarbamate over anhydrous zinc acetate |
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| Authors: | Fu-kui Xiao De-sheng Zhang Qing-nian Dong Wei Wei and and Yu-han Suna |
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| Institution: | (1) State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Graduate School of Chinese Academy of Sciences, Research Institute of Jilin Petrochemical Company, Petrochina, Taiyuan 030001, P. R. China Beijing 100039, P. R. China Jilin 132021 , P. R.China;(2) Research Institute of Jilin Petrochemical Company, Petrochina, Jilin 132021 , P. R.China;(3) State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences,, Taiyuan 030001, P. R. China;(4) State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences,, Taiyuan 030001, P. R. China;(5) State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences,, Taiyuan 030001, P. R. China |
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| Abstract: | Summary The FT-IR characterization showed that anhydrous zinc acetate hardly interacted with dimethyl carbonate, but it could coordinate
with 1,5-naphthalene diamino to form a new complex. As a result, a new mechanism on 1,5-naphthalene diamino activation was
proposed for the methoxycarbonylation of 1,5-naphthalene diamino with dimethyl carbonate over anhydrous zinc acetate. |
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