Polar effect in the reaction of CH3O with HBr |
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| Authors: | Edit Farkas Gergely Kovács Krisztina Imrik István Szilágyi Sándor Dóbé and Ferenc Márta |
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| Institution: | (1) Chemical Research Center, Hungarian Academy of Sciences Pusztaszeri út 59-67, H-1025, Budapest, Hungary |
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| Abstract: | The discharge flow method with laser induced fluorescence detection of CH3O was applied to determine the rate constant, k
1, for the reaction CH3O + HBr → products (1) k
1 (298 K) = (8.41 ± 0.80(1σ)) 1011 cm3 mol-1 s-1. The unusually large k
1 value was explained by the polar nature of the transition state of the reaction.
This revised version was published online in June 2006 with corrections to the Cover Date. |
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| Keywords: | Rate constant CH3O HBr |
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