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Influence of transition metal ions on the textural properties of alumina and aluminasilicates
Authors:Ern&#; E Kiss and Paula S Putanov
Institution:(1) Faculty of Technology, University of Novi Sad, Bul.Cara Lazara 1, 21000 Novi Sad, Serbia & Montenegro;(2) Serbian Academy of Sciences and Arts Knez, Mihajlova 35, 11000 Belgrade, Serbia & Montenegro
Abstract:Accelerated phase transformations and chemical reactions of metastable aluminas and kaolinite, doped with Cu2 +, Mn3 +/Mn2 + and Fe3 +/Fe2 + ions, are accompanied with accelerated decrease of surface area and pore volume values. The phenomena in metal ion doped samples are explained by a catalytic mechanism, in terms of the Jahn-Teller effect. This revised version was published online in June 2006 with corrections to the Cover Date.
Keywords:kaolinite  Jahn-Teller effect  Alumina  textural properties
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