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Oxidative dehydrogenation of ethane with carbon dioxide over sulfated zirconia supported metal oxides catalysts
Authors:Shaobin Wang  Kazuhisa Murata  Takashi Hayakawa  Satoshi Hamakawa and Kunio Suzuki
Institution:(1) Department of Surface Chemistry, National Institute of Materials and Chemical Research, 305 Tsukuba, Ibaraki, Japan
Abstract:Several metal oxides supported on sulfated zirconia catalysts were tested for the oxidative dehydrogenation of ethane into ethylene by carbon dioxide. It is found that the catalytic behavior of supported oxide catalysts differ depending on the nature of metal oxides. Chromium oxide-sulfated zirconia exhibits the highest ethane conversion and medium level of ethylene selectivity, producing 38% ethylene yield at 50% ethane conversion at 650°C.
Keywords:Dehydrogenation  ethylene  sulfated zirconia  carbon dioxide  metal oxides
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