Molybdovanadophosphoric Acid Catalyzed Oxidation of Hydrocarbons by H2O2 to Oxygenates |
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| Authors: | Nirupa A Alekar S B Halligudi R Rajani S Gopinathan and C Gopinathan |
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| Institution: | (1) Inorganic Chemistry and Catalysis Division, National Chemical Laboratory, Pune, 411 008, India |
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| Abstract: | Heteropoly acids of the general formula H3+xPMo12-xVxO40] (where x = 1,2,3) catalyzed the oxidation of aromatic hydrocarbons at 65°C with H2O2 to give oxygenated products. Among the catalysts, H4PMo11VO40] was found to be a more active catalyst and its activities have been reported in the oxidation of cyclohexane, methyl cyclohexane, naphthalene, 1-methyl naphthalene and biphenyl. |
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| Keywords: | Molybdovanadophosphoric acid H2O2 oxidation hydrocarbons |
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