Catalytic hydrogenation of C60 on transition metals |
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| Authors: | Toshihiko Osaki Tomoki Hamada and Yutaka Tai |
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| Institution: | (1) National Institute of Advanced Industrial Science and Technology (AIST), 2266-98 Anagahora, Shimoshidami, Moriyama-ku, Nagoya 463-8560, Japan;(2) Daido Institute of Technology, Takiharu-cho, Minami-ku, Nagoya 457-8530, Japan |
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| Abstract: | The catalytic hydrogenation of C60 on Ru, Rh and Ir produced C60H18 mainly, while Pd, Pt, Co and Ni catalysts gave C60H36 principally. Very little activity was observed on Au and Fe. The higher hydrogenated fullerene obtained on Pd, Pt, Co and
Ni was ascribed to the smaller % d-character of the metallic bond, on which the fullerene and hydrogen may more strongly be
adsorbed.
This revised version was published online in August 2006 with corrections to the Cover Date. |
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| Keywords: | fullerene C60H18 C60H36 C60 hydrogenation |
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