|
|||||
|
|
Partial oxidation of methane and ethane to oxygenates over silica supported rhenium oxide |
|
| Authors: | Ye Wang Kiyoshi Otsuka and Huilin Wan |
| Institution: | (1) State Key Laboratory for Physical Chemistry of Solid Surfaces, Department of Chemistry, Xiamen University, Xiamen, 361005, China;(2) Department of Applied Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology, Ookayama, Meguro-ku, Tokyo 152-8552, Japan |
| Abstract: | Silica supported rhenium oxide has been studied for partial oxidation of methane and ethane with oxygen. Loading of rhenium oxide on silica remarkably increases the conversions of methane and ethane. The presence of rhenium oxide increases the selectivity to useful oxygenates, particularly in ethane oxidation. The results suggest that rhenium oxide not only activates methane or ethane but also enhances oxygen transfer to form oxygenates. This revised version was published online in June 2006 with corrections to the Cover Date. |
| Keywords: | ethane partial oxidation methane oxygenates rhenium oxide |
| 本文献已被 SpringerLink 等数据库收录！ | |