Study on the combustion kinetic characteristics of biomass tar under catalysts |
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Authors: | C Li Y Yamamoto M Suzuki D Hirabayashi K Suzuki |
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Institution: | (1) EcoTopia Science Institute, Nagoya University, Nagoya 464-8603, Japan |
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Abstract: | TG and DTA experiments were performed to investigate the biomass tar combustion behavior in coexistence of dolomite and mayenite
at two different heating rates as 5 and 15°C min−1. Different reaction kinetic mechanisms with the classical Arrhenius model were used to treat TG data, and showed that the
first-order combustion model fitted the data well. Three stages combustion model was proposed and applied for the calculation
of kinetics parameters successfully. The starting temperature of high temperature combustion stage moved up near 100°C because
of the coexistence catalysts, and the combustion amount of biomass of the stage also improved nearly 10 mass%. By calculation
a uniform trend of decreasing activation energies was observed with the addition of dolomite and mayenite, and also greatly
improved the amount and speed of tar combustion process. |
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Keywords: | biomass tar combustion dolomite kinetic model mayenite TG |
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