Evolved
gas analysis at thermal treatment of some solid fossil fuels |
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Authors: | T Kaljuvee M Radin D Astahhov Y Pelovski |
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Institution: | (1) Laboratory of Inorganic Materials, Tallinn University of Technology, Tallinn, Estonia, 19086, Ehitajate tee 5;(2) University of Chemical Technology and Metallurgy, Sofia, Bulgaria, 1756, 8 Kl. Ohridski Blvd |
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Abstract: | Coupled
TG-FTIR technique was used for identification of gaseous compounds evolved
at thermal treatment of six coal samples from different deposits (Bulgaria,
Russia, Ukraine). The experiments were carried out under dynamic heating conditions
up to 900°C at heating rates of 5, 10 or 50 K min–1
in a stream of dry air. The emission of CO2, H2O,
CO, SO2, COS, methane, methanol, formic acid, formaldehyde,
acetaldehyde, chlorobenzene was clearly identified in FTIR spectra of the
samples studied. The formation of ethanol, ethane, ethylene and p-xylene, at least on the level of traces, was also
identified. At the heating rate of 5°C min–1
the temperature of maximum intensities of the characteristic peaks of COS
was 270°C, of formaldehyde, formic acid, ethane and methanol 330°C,
of SO2, CO, acetic acid, ethylene and p-xylene
400°C and of chlorobenzene 500°C. At 10°C min–1
and 50°C min–1 these temperatures were
shifted, respectively, by 70–300°C and 150–450°C towards
higher temperatures and the respective absorption bands in FTIR spectra were,
as a rule, more intensive. |
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Keywords: | coal EGA TG-FTIR thermal treatment |
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