Thermal decomposition of Me3SnO2PCl2, Me2Sn(O2PCl2)2 and Ph3SnO2PCl2 |
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| Authors: | A -F Shihada A A Said R Al Qasmi |
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| Institution: | (1) Department of Chemistry, College of Science, United Arab Emirates University, P.O. Box 17551 UAE, Al-Ain;(2) Present address: Chemistry Department, Faculty of Science, Assiut University, Assiut, Egypt |
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| Abstract: | TG and DTA studies on Me3SnO2PCl2, Me2Sn(O2PCl2)2 and Ph3SnO2PCl2 were carried out under dynamic argon atmosphere. The results show that the decomposition proceeds in different stages leading
to the formation of Sn3(PO4)2 as a stable product. This compound was characterized by IR spectroscopy. Decomposition schemes involving reductive elimination
reactions were proposed. |
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| Keywords: | IR Me2Sn(O2PCl2)2 Me3SnO2PCl2 Ph3SnO2PCl2 TG-DTA |
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