Steady-State Approximation. 5 |
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| Authors: | C Popescu E Urbanovici E Segal |
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| Institution: | (1) LACECA Research Centre, Str. Siret 95, 78308 Bucharest;(2) Department of Physical Chemistry, Faculty of Chemistry, University of Bucharest, Bd. Republicii, Nr. 13, Bucharest, Romania |
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| Abstract: | The example of the sequence of reactions and the steady-state approximation are used to present a demonstration of the fact that the evolution of the reaction rates
under non-isothermal conditions depends on the ratio of the activation energies and on the heating rate. At the same time,
it is shown that, under isothermal conditions, the ratio of the activation energies plays no role.
This revised version was published online in August 2006 with corrections to the Cover Date. |
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| Keywords: | activation energy non-isothermal kinetics steady-state approximation |
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