Thermal Stability of Some Polynuclear Coordination Compounds in the Systems Ln(III)—Co(II)—Oxalate |
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| Authors: | Badea M Olar R Cristurean E Marinescu D Brezeanu M Balasoiu M Segal E |
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| Institution: | (1) Department of Inorganic Chemistry, Bucharest University, 23 Dumbrava Rosie St., Bucharest, Romania;(2) Institute of Physical Chemistry, 202, Spl. Independentei, RO-77208 Bucharest, Romania;(3) Department of Physical Chemistry, University of Bucharest, Bulevardul Elisabeth 4-12, Bucharest, Romania |
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| Abstract: | This paper reports an investigation of the thermal stabilities of the class of coordination compounds containing lanthanide ions Ln(III) (Ln=La, Sm, Eu, Dy, Er), Co(II) ions and oxalate anions C2O
4
2–
. The thermal decomposition steps were identified, and in some cases the values of the non-isothermal kinetic parameters were determined.This revised version was published online in November 2005 with corrections to the Cover Date. |
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| Keywords: | Ln(III)– Co(II) coordination compounds non-isothermal kinetics thermal stability |
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