受阻Lewis酸碱对(Frustrated Lewis Pairs,FLPs)是一类具有特殊反应活性的Lewis酸碱对。自发现以来,FLPs受到了广泛关注并在许多领域崭露头角。本文对FLPs在不对称氢化、高分子聚合、CO_2催化还原等应用领域取得的突破进行了介绍;同时对过渡金属FLPs和FLPs配位的过渡金属催化体系进行了综述;最后对FLPs领域未来的发展前景进行了展望。
Research Progress on Frustrated Lewis Pairs Chemistry
LIU Han-Yu;YANG Zhong-Tian;YU Zi-Di;MI Tian-Xiong;BIAN Jiang.Research Progress on Frustrated Lewis Pairs Chemistry[J].University Chemistry,2016,31(4):1-11.
College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China
Abstract:
Frustrated Lewis Pairs (FLPs) represent a class of Lewis acids and bases possessing unique reactivities. Since their discovery, FLPs have obtained extensive attention and have grown rapidly on a broad range of studies. This paper highlights the application of FLPs in the fields of asymmetric hydrogenation, polymerization and catalytic reduction of CO2. Transition-metal FLPs and complexes containing FLPs ligands are also reviewed. Finally the trend in the development of FLPs is also discussed.
