| 环己酮制备实验的改进 |
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| 引用本文： | 张思雨,郝天辉,王则月,姚赟,凌剑,赵静峰.环己酮制备实验的改进[J].大学化学,2020,35(4):168-172. |
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| 作者姓名： | 张思雨 郝天辉 王则月 姚赟 凌剑 赵静峰 |
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| 作者单位： | 云南大学化学科学与工程学院;云南大学教育部自然资源药物化学重点实验室 |
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| 基金项目： | 云南省教改项目(JG2018025)。 |
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| 摘 要： | 以环己醇合成环己酮在大学有机化学基础实验教学中占有重要地位,但是目前实验教学主要使用的方法是重铬酸钠-浓硫酸氧化法,使用强腐蚀性的浓硫酸,并产生含铬强酸性有毒废液。本文采用NaClO-TEMPO-TBAB催化氧化反应,缩短实验时间,提高产率并实现了半微型化实验,在达到同样教学目的的同时避免了原有实验带来的铬污染和强酸问题。
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| 关 键 词： | 环己醇 环己酮 催化氧化 相转移催化 |
| 收稿时间： | 2019-11-20 |
Improvement of the Cyclohexanone Preparation Experiment |
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| Siyu Zhang,Tianhui Hao,Zeyue Wang,Yun Yao,Jian Ling,Jingfeng Zhao.Improvement of the Cyclohexanone Preparation Experiment[J].University Chemistry,2020,35(4):168-172. |
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| Authors: | Siyu Zhang Tianhui Hao Zeyue Wang Yun Yao Jian Ling Jingfeng Zhao |
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| Institution: | 1. School of Chemical Science and Technology, Yunnan University, Kunming 650091, P. R. China;2. Key Laboratory of Medicinal Chemistry for Natural Resource, Ministry of Education, Yunnan University, Kunming 650091, P. R. China |
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| Abstract: | The cyclohexanone preparation is an important experiment in fundamental organic chemistry laboratory for college students. In this paper, NaClO-TEMPO-TBAB catalytic oxidation reaction was used to replace chromic acid oxidation reaction, avoiding concentrated sulfuric acid and chromium-containing waste. At the same time, the reaction conditions were optimized to achieve small scale and shorten operating time which can train and improve students' operation skills in the experiment. |
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| Keywords: | Cyclohexanol Cyclohexanone Catalytic oxidation Phase transfer catalysis |
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