| CO加氢制备低碳烯烃Fe基和Co基催化剂研究进展 |
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| 引用本文： | 唐立平,宋承立,王健,贾晶晶.CO加氢制备低碳烯烃Fe基和Co基催化剂研究进展[J].分子催化,2019,33(5):486-493. |
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| 作者姓名： | 唐立平 宋承立 王健 贾晶晶 |
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| 作者单位： | 滨州学院 化工与安全学院, 山东 滨州 256603,中国科学院兰州化学物理研究所 羰基合成与选择氧化国家重点实验室, 甘肃 兰州 730000,滨州学院 学报编辑部, 山东 滨州 256603,滨州学院 化工与安全学院, 山东 滨州 256603 |
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| 基金项目： | 滨州学院博士学位人员及具有硕士学位的高级职称人员科研启动经费项目（No.2018Y16） |
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| 摘 要： | CO加氢制备低碳烯烃是非石油路线获得烯烃的重要反应,其反应路线有直接法和间接法.直接法制备低碳烯烃具有反应路线短、能源利用率高、经济高效等优势.综述了近年来Fe基催化剂、 Co基催化剂在CO直接制备低碳烯烃中的研究进展.分析认为:费托合成过程产物选择性遵循Anderson-Schulz-Flory(ASF)分布规律,助剂和载体的使用一定程度提高Fe基、 Co基催化剂的低碳烯烃选择性.
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| 关 键 词： | 费托合成 CO加氢 Fe基催化剂 Co基催化剂 低碳烯烃 |
| 收稿时间： | 2019/7/25 0:00:00 |
| 修稿时间： | 2019/9/10 0:00:00 |
Recent Advances in The Development of Fe-based and Co-based Catalysts for CO Hydrogenation to Light Olefins |
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| TANG Li-ping,SONG Cheng-li,WANG Jian and JIA Jing-jing.Recent Advances in The Development of Fe-based and Co-based Catalysts for CO Hydrogenation to Light Olefins[J].Journal of Molecular Catalysis (China),2019,33(5):486-493. |
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| Authors: | TANG Li-ping SONG Cheng-li WANG Jian and JIA Jing-jing |
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| Institution: | Department of Chemical Engineering and Safety, Binzhou University, Binzhou 256603, China,The State Key Laboratory of Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China,Editorial Department of Journal, Binzhou University, 256603, China and Department of Chemical Engineering and Safety, Binzhou University, Binzhou 256603, China |
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| Abstract: | CO hydrogenation to light olefins is an important non-petroleum route to obtain olefins and the reaction routes include direct and indirect methods. Direct synthesis progress of light olefins has the advantages of short reaction route, high energy utilization and high economic efficiency. This paper reviews the recent research progress of Fe-based catalysts and Co-based catalysts. The products in Fischer-Tropsch synthesis follows Anderson-Schulz-Flory (ASF) distribution law and the selectivity of light olefins can be improved by using suitable promoters and carriers in the Fe-based and Co-based catalysts. |
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| Keywords: | fischer-tropsch synthesis CO hydrogenation Fe-based catalyst Co-based catalyst light olefin |
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