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| MCM-41表面氧化铜的分散研究 | |
| 引用本文： | 郝向英,张翠,张寅清,王振宇,刘双喜.MCM-41表面氧化铜的分散研究[J].分子催化,2006,20(1):73-75. |
| 作者姓名： | 郝向英 张翠 张寅清 王振宇 刘双喜 |
| 作者单位： | 1. 南开大学化学学院,新催化材料科学研究所,天津,300071;内蒙古师范大学,化学与环境科学学院,呼和浩特,010022 2. 南开大学化学学院,新催化材料科学研究所,天津,300071 3. 南开大学,催化剂厂,天津,300071 |
| 基金项目： | 中国科学院资助项目;南开大学-天津大学联合研究院教育部南开大学、天津大学科技合作项目 |
| 摘 要： | 金属离子修饰的M41S介孔分子筛催化剂体系是当前多相催化剂研究的热点.虽然有关介孔分子筛金属离子修饰的方法有多种1],但均存在着负载的金属粒子在载体表面负载量低或分散不均匀等缺点;采用本课题组的有机官能团化法2]可以得到高分散度和高负载量的介孔分子筛负载金属氧化物 |
| 关 键 词： | MCM-41 氧化铜 分散 有机官能团化 |
| 文章编号： | 1001-3555(2006)01-0073-03 |
| 收稿时间： | 2005-08-28 |
| 修稿时间： | 2005-09-27 |
Study on the Dispersion of CuO on the MCM-41 Surface |
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| HAO Xiang-ying,ZHANG Cui,ZHANG Yin-qing,WANG Zhen-yu,LIU Shuang-xi.Study on the Dispersion of CuO on the MCM-41 Surface[J].Journal of Molecular Catalysis (China),2006,20(1):73-75. | |
| Authors: | HAO Xiang-ying ZHANG Cui ZHANG Yin-qing WANG Zhen-yu LIU Shuang-xi |
| Institution: | 1. Institute of New Catalytic Materials Science, College of Chemistry, Nankai University, Tianjin 300071, China ; 2. College of Chemistry and Environmental Science, inner Mongolia Normal University, Huhhot, 010022, China; 3. Catalyst Plant of Nankai University, Tianjin 300071, China |
| Abstract: | MCM-41 supporting CuO was prepared in the present research by immobilizing metal ions with organofunctionalized MCM-41 and subsequent ultrasonic washing and calcination.The coordination of Cu(II) with organic functionalized MCM-41 as well as the formation of CuO on the molecular sieve surface during the calcination process were investigated by FTIR and In-situ Drift FTIR. |
| Keywords: | MCM-41 CuO Dispersion Organofunctionalization |
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