| 钯-膦-酸体系催化烯烃氢酯基化反应研究进展 |
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| 引用本文： | 鲁艳梅,兰永成,郧栋,夏春谷,刘建华.钯-膦-酸体系催化烯烃氢酯基化反应研究进展[J].分子催化,2022,36(4):360-373. |
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| 作者姓名： | 鲁艳梅 兰永成 郧栋 夏春谷 刘建华 |
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| 作者单位： | 中国科学院兰州化学物理研究所,中国科学院兰州化学物理研究所,中国科学院兰州化学物理研究所,中国科学院兰州化学物理研究所,中国科学院兰州化学物理研究所 |
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| 基金项目： | 国家自然科学基金项目（面上项目，重点项目，重大项目） |
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| 摘 要： | 烯烃氢酯基化反应是羰基合成领域的重要分支之一，长期以来一直备受关注。目前已发展了钯基、铑基、钴基、钌基等众多催化体系，其中钯-膦-酸催化体系因具有反应条件温和、底物普适性良好、催化性能优异等优点而得到最广泛、最深入的研究。因此，我们对均相、非均相的钯-膦-酸催化体系在烯烃氢酯基化反应中的研究应用进行了简要综述，并对催化机理、催化剂组成和性能进行讨论，最后指出稳定性高、可回收性好的非均相钯-膦-酸催化体系将是该领域的研究重点。
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| 关 键 词： | 氢酯基化 钯-膦-酸催化体系 负载型催化剂 两相体系 |
| 收稿时间： | 2022/3/19 0:00:00 |
| 修稿时间： | 2022/4/12 0:00:00 |
Research Progress of Alkene Hydroesterification Catalyzed by Palladium-phosphine-acid System |
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| LU Yan-mei,LAN Yong-cheng,YUN Dong,XIA Chun-gu and LIU Jian-hua.Research Progress of Alkene Hydroesterification Catalyzed by Palladium-phosphine-acid System[J].Journal of Molecular Catalysis (China),2022,36(4):360-373. |
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| Authors: | LU Yan-mei LAN Yong-cheng YUN Dong XIA Chun-gu and LIU Jian-hua |
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| Institution: | State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences, Lanzhou 730000, China;University of Chinese Academy of Sciences, Beijing 100049, China,State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences, Lanzhou 730000, China;University of Chinese Academy of Sciences, Beijing 100049, China,State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences, Lanzhou 730000, China,State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences, Lanzhou 730000, China and University of Chinese Academy of Sciences, Beijing 100049, China |
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| Abstract: | Alkene hydroesterification is an important branch of carbonyl synthesis, which has attracted much attention for a long time. At present, Pd based, Rh based, Co based, Ru based and other catalytic systems have been developed. Among them, palladium-phosphine-acid system has been the most widely and deeply studied because of its mild reaction conditions, good substrate universality and excellent catalytic performance. Therefore, the research and application of homogeneous and heterogeneous palladium-phosphine-acid catalytic system in alkene hydroesterification are briefly reviewed, and the catalytic mechanism, catalyst composition and performance are discussed. Finally, it is pointed out that the heterogeneous palladium-phosphine-acid catalytic system with high stability and good recoverability will be the research focus in this field. |
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| Keywords: | Hydroesterification Pd/phosphine/acid catalyst Supported catalyst Two-phase system |
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