| 基于吡咯骨架的不对称傅克反应研究进展 |
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| 引用本文： | 安士云,魏钊,张金龙,蒋高喜.基于吡咯骨架的不对称傅克反应研究进展[J].分子催化,2020,34(3):261-271. |
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| 作者姓名： | 安士云 魏钊 张金龙 蒋高喜 |
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| 作者单位： | 中国科学院兰州化学物理研究所,中国科学院兰州化学物理研究所,中国科学院兰州化学物理研究所,中国科学院兰州化学物理研究所 |
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| 基金项目： | 国家自然科学基金（21602231），江苏省自然科学基金（BK20160396 and BK20191197） |
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| 摘 要： | 手性吡咯化合物是一类重要的五元含氮杂环化合物,广泛存在于众多有生物活性的天然产物中.利用不对称傅克反应合成手性吡咯化合物一直是有机合成的研究热点之一.利用手性有机小分子和手性金属催化剂是实现不对称合成手性吡咯化合物最为常见的方法.根据催化剂的分类,我们就近十几年来基于吡咯结构单元的不对称傅克反应的研究进展进行简要阐述.
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| 关 键 词： | 不对称催化 吡咯化合物 傅克反应 |
| 收稿时间： | 2020/5/14 0:00:00 |
| 修稿时间： | 2020/5/18 0:00:00 |
Recent Progress in Asymmetric Catalytic Friedel-Crafts Reaction of Pyrroles |
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| AN Shi-yun,WEI Zhao,ZHANG Jin-long and JIANG Gao-xi.Recent Progress in Asymmetric Catalytic Friedel-Crafts Reaction of Pyrroles[J].Journal of Molecular Catalysis (China),2020,34(3):261-271. |
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| Authors: | AN Shi-yun WEI Zhao ZHANG Jin-long and JIANG Gao-xi |
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| Institution: | The Lanzhou Institute of Chemical Physics of the Chinese Academy of Sciences,The Lanzhou Institute of Chemical Physics of the Chinese Academy of Sciences,The Lanzhou Institute of Chemical Physics of the Chinese Academy of Sciences,The Lanzhou Institute of Chemical Physics of the Chinese Academy of Sciences |
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| Abstract: | Chiral pyrroles are always found in many biologically active natural products. In recent years, asymmetric catalytic Friedel-Crafts (F-C) reaction of pyrroles has become one of the research focuses. Asymmetric organo-catalysis and transition-metal catalysis are often used in asymmetric catalytic synthesis of chiral pyrroles. According to the classification of the catalyst, the research progress in the asymmetric catalytic F-C reaction of pyrroles is reviewed. |
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| Keywords: | Asymmetric catalysis Pyrroles Friedel-Crafts Reaction |
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