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| TiO2-Al2O3复合氧化物负载NiMo加氢脱硫催化剂的研究 | |
| 引用本文： | 刘百军,郑宇印,孟庆民,蒋应田,盛世善,杨维慎,熊国兴.TiO2-Al2O3复合氧化物负载NiMo加氢脱硫催化剂的研究[J].分子催化,2004,18(6):447-451. |
| 作者姓名： | 刘百军 郑宇印 孟庆民 蒋应田 盛世善 杨维慎 熊国兴 |
| 作者单位： | 1. 石油大学(北京)化工学院CNPC催化重点实验室,北京,102249 2. 辽宁石油化工大学,机械工程学院,辽宁,抚顺,113001 3. 中国科学院大连化学物理研究所,催化基础国家重点实验室,大连,116023 |
| 基金项目： | 中国石油天然气集团公司石油科技中青年创新基金(2002 CX 32)和中科院大连化物所催化基础国家重点实验室开放课题(02-G014). |
| 摘 要： | 采用溶胶凝胶技术，从Al2O3载体的表面改性出发，制备了TiO2-Al2O3复合载体。采用此改性载体制备了NiMo／TiO2-Al2O3催化剂；用中压固定床微反装置考察了载体改性对制备的催化剂的噻吩加氢脱硫(HDS)活性的影响．用透射电镜、NH3-TPD及吡啶红外光谱法对改性载体和催化剂进行了表征．结果表明，经钛溶胶改性的载体制备的催化剂与原有载体制备的催化剂相比，催化剂活性提高了20％．改性载体表面负载的钛溶胶以纳米尺寸的TiO2微粒形态存在． |
| 关 键 词： | 溶胶凝胶技术 催化剂 加氢脱硫 TiO2改性 |
| 文章编号： | 1001-3555(2004)06-0447-05 |
| 修稿时间： | 2003年9月17日 |
Tatania Modification of Al2O3 Support and Hydrodesulphurization Activity |
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| LIU Bai-jun,ZHENG Yu-yin,MENG Qing-min,JIANG Ying-tian,SHENG Shi-shan,YANG Wei-shen,XIONG Guo-xinging,Beijing,Chin,School of Mechanical Engineering,Liaoning University of Petroleum and Chemical Technology,Fushun,Chin,The Chinese Academy of Scinces,Dalian,China.Tatania Modification of Al2O3 Support and Hydrodesulphurization Activity[J].Journal of Molecular Catalysis (China),2004,18(6):447-451. | |
| Authors: | LIU Bai-jun ZHENG Yu-yin MENG Qing-min JIANG Ying-tian SHENG Shi-shan YANG Wei-shen XIONG Guo-xinging Beijing Chin School of Mechanical Engineering Liaoning University of Petroleum and Chemical Technology Fushun Chin The Chinese Academy of Scinces Dalian China |
| Institution: | LIU Bai-jun~1,ZHENG Yu-yin~1,MENG Qing-min~1,JIANG Ying-tian~2,SHENG Shi-shan~3,YANG Wei-shen~3,XIONG Guo-xing~3ing),Beijing 102249,China, 2 School of Mechanical Engineering,Liaoning University of Petroleum and Chemical Technology,Fushun 113001,China,,The Chinese Academy of Scinces,Dalian 116023,China) |
| Abstract: | TiO_2-Al_2O_3 complexing support was prepared by sol\|gel technology and Ni-Mo/TiO_2-Al_2O_3 catalysts were prepared by impregnation with the modified supports. The influence of support modification on the hydrodesulphurization (HDS) activity of the catalysts was evaluated by a fixed-bed microreactor under moderate-pressure. The modified supports and catalysts were characterized by TEM, pyridine-IR and NH_3-TPD. The experimental results revealed that the activity of catalyst supported on titania sol modified support was improved for 20% compared with catalyst supported on unmodified supports. The TEM photos showed that titania was in nanometer grain on the surface of support. When the titania sol loading is below 5.0 wt%, the activity of catalyst increases with the increasing of the titania sol loading. |
| Keywords: | Sol-gel technology Catalyst Hydrodesulphurization Titania modification |
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