| TiO_2/Fe-杭锦2~#土催化剂光催化降解废水中乙酸的研究 |
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| 引用本文： | 萨仁其其格,萨嘎拉,贾美林,照日格图.TiO_2/Fe-杭锦2~#土催化剂光催化降解废水中乙酸的研究[J].分子催化,2017,31(6):523-533. |
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| 作者姓名： | 萨仁其其格 萨嘎拉 贾美林 照日格图 |
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| 作者单位： | 内蒙古自治区绿色催化重点实验室 内蒙古师范大学化学与环境科学学院, 内蒙古 呼和浩特 010022,内蒙古自治区绿色催化重点实验室 内蒙古师范大学化学与环境科学学院, 内蒙古 呼和浩特 010022,内蒙古自治区绿色催化重点实验室 内蒙古师范大学化学与环境科学学院, 内蒙古 呼和浩特 010022,内蒙古自治区绿色催化重点实验室 内蒙古师范大学化学与环境科学学院, 内蒙古 呼和浩特 010022 |
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| 基金项目： | 内蒙古自然科学基金（2014MS0213）；内蒙古自治区重点实验室能力建设资助项目；内蒙古师范大学研究生科研创新基金（CXJJS16093）；内蒙古自治区水环境安全协同创新培育中心（XTCX003）；内蒙古自治区科技创新引导项目（21090147） |
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| 摘 要： | 首先采用离子交换法制得Fe-杭锦2#土,以其为载体使用溶胶-凝胶法制备了TiO_2/Fe-杭锦2#土负载型光催化剂,并通过X射线粉末衍射(XRD)、氮气吸附脱附(N2-BET)、固体紫外可见漫反射(UV-Vis DRS)、X射线光电能谱(XPS)和扫描电子显微镜(SEM)分析等对催化剂进行了表征.以光催化降解乙酸为探针反应,考察了Ti的负载量、光源、光照时间、催化剂用量和反应温度等反应条件对催化剂催化性能的影响.实验结果表明,对于浓度为100 mg·L-1的乙酸溶液,选用氧化钛负载量为20%的光催化剂、300 W汞灯为光源、反应温度为50℃、反应时间为6 h、催化剂用量为50 g·L~(-1)时,对乙酸的光催化降解效果相对最优,降解率达到78.30%.
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| 关 键 词： | TiO2/Fe 光催化 降解 乙酸 杭锦2#土 |
| 收稿时间： | 2017/8/25 0:00:00 |
| 修稿时间： | 2017/9/30 0:00:00 |
Photocatalytic Degradation of Acetic Acid in Wastewater by TiO2/Fe-Hangjin 2# Catalyst |
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| Sarenqiqige,BAI Sagal,JIA Meilin and BAO Zhaorigetu.Photocatalytic Degradation of Acetic Acid in Wastewater by TiO2/Fe-Hangjin 2# Catalyst[J].Journal of Molecular Catalysis (China),2017,31(6):523-533. |
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| Authors: | Sarenqiqige BAI Sagal JIA Meilin and BAO Zhaorigetu |
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| Institution: | Inner Mongolia Key Laboratory of Green Catalysis, College of Chemistry and Environmental Science, Inner Mongolia Normal University, Hohhot 010022, China,Inner Mongolia Key Laboratory of Green Catalysis, College of Chemistry and Environmental Science, Inner Mongolia Normal University, Hohhot 010022, China,Inner Mongolia Key Laboratory of Green Catalysis, College of Chemistry and Environmental Science, Inner Mongolia Normal University, Hohhot 010022, China and Inner Mongolia Key Laboratory of Green Catalysis, College of Chemistry and Environmental Science, Inner Mongolia Normal University, Hohhot 010022, China |
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| Abstract: | TiO2/Fe-Hangjin 2# supported catalysts were prepared by sol-gel method using Fe-Hangjin 2# as support,which was developed from Hangjin 2# clay by ion-exchange method under alkaline condition.XRD,BET,UV-Vis DRS,XPS,and SEM were used to characterize these photocatalysts and their photocatalytic performances for degradation of acetic acid were studied.The effects of Ti loading,amount of catalyst,reaction temperature,light source and irradiation time on the catalytic performance were investigated.For the acetic acid solution with concentration of 100 mg · L-1,at the optimum reaction conditions,300 W mercury lamp as light source,20％ Ti loading,50 g · L-1 catalyst,reaction temperature of 50 ℃ and the reaction time of 6 h,78.3％ of degradation of acetic acid were obtained. |
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| Keywords: | TiO2/Fe photocatalytic degradation acetic acid hangjin 2# clay |
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