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Synthesis, characterization and SERS activity of Au-Ag nanorods
Authors:Philip Daizy  Gopchandran K G  Unni C  Nissamudeen K M
Institution:Department of Physics, Mar Ivanios College, Thiruvananthapuram 695015, India.
Abstract:The formation mechanism and morphology of Au-Ag bimetallic colloidal nanoparticles depend on the composition. Ag coated Au colloidal nanoparticles have been prepared by deposition of Ag through chemical reduction on performed Au colloid. The composition of the Au(100-x)-Ag(x) particles was varied from x=0 to 50. The obtained colloids were characterized by UV-vis spectroscopy and transmission electron microscopy (TEM). The Au(80)-Ag(20) colloid consists of alloy nanorods with dimension of 25nmx100nm. The activity of these nanorods in surface enhanced Raman spectroscopy (SERS) was checked by using sodium salicylate as an adsorbate probe. Intense SERS bands are observed indicating its usefulness as a SERS substrate in near infrared (NIR) laser excitation.
Keywords:Gold nanoparticles  Mixed Au–  Ag nanoparticles  Au–  Ag alloy nanorods  UV–  vis spectra  TEM  SERS  NIR laser excitation  Sodium salicylate
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