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Predictable site-selective radical fluorination of tertiary ethers |
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| Authors: | Ma Junyang Xu Wentao Xie Jin |
| Institution: | 1.State Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, Chemistry and Biomedicine Innovation Center, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210023, China ; |
| Abstract: | Science China Chemistry - In this communication, we disclose the first example of metal-free and site-selective radical fluorination of readily available tertiary alkyl ethers, enabled by... |
| Keywords: | cooperative catalysis C–O bond activation radical fluorination polarity-matching effect umpolung |
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