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Zeolite NaY-mediated oxidation of dyes with H2O2: unique heterogeneous non-transition metal center cleavage of H2O2 under visible light irradiation
Authors:LiLi Liu  WanHong Ma  WenJing Song  ChunCheng Chen  Jun Lin  JinCai Zhao  XinHua Qian  ShiBo Zhang
Institution:1. Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100080, China
2. Department of Chemistry, Renmin University of China, Beijing, 100872, China
3. Fushun Petrochemical Company, PetroChina Company Limited, Fushun, 113008, China
Abstract:This study investigated the visible-light catalysis mediated by zeolite NaY on the oxidation of dyes with H2O2. The results demonstrated that zeolite NaY acts as a sink for the electron from the photo-excited dye in the heterogeneous catalysis. Furthermore, the electron can effectively activate H2O2 to produce ·OH radical that is a powerful oxidant for the oxidation of dye at room temperature. The effects of the framework topology, Si/Al ratio, and exchangeable cation of the zeolite on the oxidation of various dyes were also shown.
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