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恒电压下百草枯和阿特拉津在纳米通道中迁移特性研究
引用本文:代国帅,史汶灵,黄杉生.恒电压下百草枯和阿特拉津在纳米通道中迁移特性研究[J].分析试验室,2012,31(1):6-10.
作者姓名:代国帅  史汶灵  黄杉生
作者单位:上海师范大学生命与环境科学学院,上海,200234
基金项目:国家高技术研究发展计划项目(863计划)课题,上海市科委创新行动计划项目
摘    要:采用化学沉积法将金沉积到聚碳酸酯膜内孔壁,制备了呈负电性的阵列金纳米通道.在外加恒电压作用下,阳离子型的百草枯选择性通过负电性的金纳米通道,阿特拉津为分子型化合物,不受电荷选择性和电泳作用影响,难以在金纳米通道内迁移.借此,可实现二者的分离.

关 键 词:金纳米通道  电荷选择性  百草枯  阿特拉津  分离

Study of paraquat and atrazine through nanochannels under a constant voltage
DAI Guo-shuai , SHI Wen-ling , HUANG Shan-sheng.Study of paraquat and atrazine through nanochannels under a constant voltage[J].Chinese Journal of Analysis Laboratory,2012,31(1):6-10.
Authors:DAI Guo-shuai  SHI Wen-ling  HUANG Shan-sheng
Institution:*(Life and Environmental Science College,Shanghai Normal University,Shanghai 200234)
Abstract:The nanotubule negatively charged were prepared by depositing gold onto the walls of pores of polycarbonate membrane using an electroless plating method.Paraquat positively charged can transport through the nanotubule membrane,whereas atrazine,a molecular compounds,is more difficult to transport through the nanotubule negatively charged than paraquat due to the charge selectivity and electrophoresis.Paraquat and atrazine can be separated based on this nanotubule membrane.
Keywords:Gold nanochannel  Charge selectivity  Paraquat  Atrazine  Separation
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