| 配合物Ru(dcbpy)(phen)2(PF6)2的2D-NMR分析 |
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| 引用本文： | 王鹏,朱果逸.配合物Ru(dcbpy)(phen)2(PF6)2的2D-NMR分析[J].分析试验室,1999,18(4):14-17. |
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| 作者姓名： | 王鹏 朱果逸 |
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| 作者单位： | 中国科学院长春应用化学研究所电分析化学开放研究实验室,国家电化学和光谱分析研究中心,长春,130022 |
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| 摘 要： | 用一维ＮＭＲ方法研究了新型电化学发光探针Ｒｕ（ｄｃｂｐｙ）（ｐｈｅｎ）２（ＰＦ６）２的立体结构，借助二维＾１Ｈ－＾１Ｈ ＣＯＳＹ和＾１Ｈ－＾１３Ｃ ＣＯＳＹ实验对其氢谱和碳谱进行了完全的归属，并给出了其氢谱和碳谱的化学位移值。
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| 关 键 词： | 电化学发光探针 |
| 文章编号： | 1000-0720(1999)
04-014-04 |
2D NMR Analysis of Ru(dcbpy)(phen)2(PF6)2 Complex |
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| WANG Peng,ZHU Guo-yi.2D NMR Analysis of Ru(dcbpy)(phen)2(PF6)2 Complex[J].Chinese Journal of Analysis Laboratory,1999,18(4):14-17. |
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| Authors: | WANG Peng ZHU Guo-yi |
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| Abstract: | y using the
reaction of Ru(1,10phenanthroline)2Cl2 with 2,2bipyridine4,4dicarboxylic acid refluxed in
methanol and water,a new complex that has excellent property of electrochemiluminescence
was synthesized.The complex was characterized by means of NMRHowever,because of the
effect of Ru atom on ligands and steric configuration,it is difficult to attribute spectra of the title
molecule.By means of 2D1H1H COSY and1H13C COSY techniques,the NMR spectra are
assigned completely |
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| Keywords: | Ru(dcbpy)(phen)2(PF6)2 2D NMR |
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