蒋锡夔研究员及其在物理有机化学和有机氟化学领域的成就

蒋锡夔研究员是我国物理有机化学和有机氟化学的主要奠基人。本文首先介绍蒋锡夔研究员的科学经历，然后介绍他在不同时期取得的代表性科学成就，主要包括有关四氟乙烯的亲电加成反应，氟橡胶研究，亲卤反应，自由基化学及有机分子的簇集与自卷等方面的研究。

Professor Jiang Xikui and His Achievements in Physical Organic and Organofluorine Chemistry

Professor Jiang Xikui, born in 1926, is one of the pioneers in physical organic and organofluorine chemistry in China. This account first introduces Prof. Jiang’ academic background and then describes his achievements in different periods. The researches on the discovery of the electrophilic addition reaction of tetrafluoroethene, the preparation of fluoro-rubber, the discovery of the halophilic substitution reaction, the radical chemistry and the aggregation and self-coiling of organic molecules in aqueous media are emphasized.