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超声-光催化降解水中有机污染物
引用本文:王颖,牛军峰,张哲,隆兴兴.超声-光催化降解水中有机污染物[J].化学进展,2008,20(10):1621-1627.
作者姓名:王颖  牛军峰  张哲  隆兴兴
作者单位:北京师范大学环境学院水环境模拟国家重点实验室,北京,100875
基金项目:国家高技术研究发展计划(863计划),国家自然科学基金,中国博士后科学基金
摘    要:超声-光催化是一项近年发展起来的废水处理的新型高级氧化技术。该技术利用超声的空化效应、自由基效应以及机械效应强化光催化的催化效能,实现超声和光催化对水中有机污染物的协同降解。本文从水中有机污染物的超声-光催化降解机理、降解动力学、影响因素(光催化剂类型和投加量、超声频率和强度、溶液pH值、温度、反应物初始浓度、溶解性气体和离子强度)和反应器类型(悬浮型、固定床型)4个方面介绍了相关研究进展,提出了目前存在的主要问题,并展望了超声-光催化降解水中有机污染物的发展方向。

关 键 词:超声  光催化  有机污染物  降解机理  反应器
收稿时间:2007-11-07
修稿时间:2008-01-10

Sono-photocatalytic Degradation of Organic Pollutants in Water
Wang Ying,Niu Junfeng,Zhang Zheyun,Long Xingxing.Sono-photocatalytic Degradation of Organic Pollutants in Water[J].Progress in Chemistry,2008,20(10):1621-1627.
Authors:Wang Ying  Niu Junfeng  Zhang Zheyun  Long Xingxing
Institution:(The State Key Laboratory of Water Environment Simulation, School of Environment, Beijing Normal University, Beijing 100875, China)
Abstract:Sono-photocatalytic degradation of organic pollutants in wastewater is a newly-developed Advanced Oxidateion Processes (AOPs). In this process, the efficiency of photocatalysis is promoted by ultrasonic cavitation, free-radical and mechanical effects, and thus synergetic degradation of organic pollutants in wastewater is achieved. The sono-photocatalytic combined process displays a big potential because of its advantages such as simpleness, environmentally friendly and widely applications. In this paper, degradation mechanism, kinetics, influence factors (the type and concentration of photocatalyst, ultrasonic frequency and intensity, pH values, temperature, initial concentration of organic pollutants, dissolved gas and ionic strength) the type of reactor (suspension and fix bed) for the sono-photocatalytic combined process are reviewed. The main problems and prospect of sono-photocatalytic combined process for wastewater treatment are presented.
Keywords:ultrasound  photocatalysis  organic pollutants  degradation mechanism  reactors
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