| 烯烃不对称催化环丙烷化反应进展评述 |
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| 引用本文： | 姚小泉,陈惠麟,郑卓.烯烃不对称催化环丙烷化反应进展评述[J].化学进展,2000,12(3):282-295. |
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| 作者姓名： | 姚小泉 陈惠麟 郑卓 |
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| 作者单位： | 中国科学院大连化学物理研究所 大连 116023 |
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| 摘 要： | 本文从手性配体的发展出发, 综述了烯烃不对称环丙烷化反应近10 年来的研究进展, 对半咕啉、双 唑啉等C2 轴手性配体在该反应中的应用做了详细论述, 介绍了反应机理研究的最新进展, 并探讨了该反应在走向工业应用过程中所面临的主要问题。
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| 关 键 词： | 烯烃 不对称环丙烷化 C2轴手性配体 |
| 收稿时间： | 1999-07-01 |
| 修稿时间： | 1999-07-01 |
Review of Asymmetric Cyclopropanation of Olefins |
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| Yao Xiaoquan,Chen Huilin,Zheng Zhuo.Review of Asymmetric Cyclopropanation of Olefins[J].Progress in Chemistry,2000,12(3):282-295. |
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| Authors: | Yao Xiaoquan Chen Huilin Zheng Zhuo |
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| Institution: | Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China |
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| Abstract: | In this article, the progress on asymmetric cyclopropanation of olefins during the last decade was reviewed. The application of chiral C 2 symmetrical ligands in the reaction, such as bis oxazoline and semicorrin, were discussed in detail. The new development of research on mechanism was introduced. Some major difficulties in the industrial application of the reaction were summarized. |
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| Keywords: | olefin asymmetric cyclopropanation C 2 symmetrical ligands |
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