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杂多酸催化剂及其在精细化学品合成中的应用
引用本文:赵忠奎,李宗石,王桂茹,乔卫红,程侣伯.杂多酸催化剂及其在精细化学品合成中的应用[J].化学进展,2004,16(4):620-630.
作者姓名:赵忠奎  李宗石  王桂茹  乔卫红  程侣伯
作者单位:(大连理工大学精细化工国家重点实验室 大连 116023)
摘    要:详细介绍了环境友好的杂多化合物的结构、性能、制备、表征及其在精细化学品合成中的应用最新进展,并对负载型杂多酸和新颖的混合型杂多酸及其盐催化剂的合成及应用进行综述.认为杂多化合物的深入研究具有十分重要的理论价值和现实意义.杂多酸及盐作为绿色催化剂在精细化学品合成中具有广阔的应用前景.

关 键 词:杂多化合物  精细化学品  负载杂多酸  新型混和杂多酸  绿色催化剂  
文章编号:1005-281X(2004)04-0620-11
收稿时间:2003-05-01
修稿时间:2003年5月1日

Heteropoly Acids Catalysts and Their Application in the Synthesis of Fine Chemicals
Zhao Zhongkui,Li Zongshi,Wang Guiiru,Qiao Weihong,Cheng Lvbo.Heteropoly Acids Catalysts and Their Application in the Synthesis of Fine Chemicals[J].Progress in Chemistry,2004,16(4):620-630.
Authors:Zhao Zhongkui  Li Zongshi  Wang Guiiru  Qiao Weihong  Cheng Lvbo
Institution:(The State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116023, China)
Abstract:The progress of the structure, performance, synthesis and characterization of the environmentally benign heteropoly compounds and their use in fine chemicals are introduced in detail. The synthesis and application of the supported heteropoly acids and the novel mixed heteropoly compounds obtained by designing molecule are also reviewed. The research for heteropoly acids (HPA) and their salts has a quite important theoretical value and realistic meanings. HPA used as excellent green catalyst will possess extensive application prospect in fine chemical synthesis.
Keywords:heteropoly compounds  fine chemicals  supported heteropoly acids  novel mixed heteropoly acids  green catalysts
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