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纳米金催化剂上CO低(常)温氧化的研究
引用本文:王东辉,程代云,郝郑平,史喜成.纳米金催化剂上CO低(常)温氧化的研究[J].化学进展,2002,14(5):360-367.
作者姓名:王东辉  程代云  郝郑平  史喜成
作者单位:1. 防化研究院,北京,100083;中国科学院生态环境研究中心,北京,100085
2. 防化研究院,北京,100083
3. 中国科学院生态环境研究中心,北京,100085
基金项目:国家“十五”863高新技术项目 ( 2 0 0 1 AA32 4 0 5 0 )的部分资助
摘    要:金历来被认为是催化惰性的,但近年来有关金催化剂的研究与开发引起人们的兴趣与关注。负载纳米金催化剂显示了良好的催化性能,尤其对一氧化碳氧化反应,能够在低(常)温下将CO氧化为CO2。和其他CO氧化催化剂相比,金催化剂具有高的催化活性、稳定性和抗潮湿的性能,预示着更加广泛的应用前景。本文从制备方法、载体的性质、微粒粒径的大小、预处理、活性机理和催化反应机理等方面进行综合与评述。

关 键 词:负载型金催化剂  CO氧化  制备方法  载体效应  纳米微粒
文章编号:1005-281X(2002)05-0360-08
收稿时间:2001-08-01
修稿时间:2001年8月1日

Carbon Monoxide Low-temperature Oxidation over Nanosize Gold Catalyst
Wang Donghui,Cheng Daiyun,Hao Zhengping,Shi Xicheng.Carbon Monoxide Low-temperature Oxidation over Nanosize Gold Catalyst[J].Progress in Chemistry,2002,14(5):360-367.
Authors:Wang Donghui  Cheng Daiyun  Hao Zhengping  Shi Xicheng
Institution:1. Research Institute of Chemical Defence, Beijing 100083, China; 2. Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China
Abstract:Gold has long been known as being catalytically inactive. However, more interest and attention have been concentrated on the research and development of gold catalysts in recent years. Gold catalysts have been shown good catalytic performances, especially for CO oxidation, and can be used to eliminate CO even below ambient temperature. Compared with other catalysts for CO oxidation, the nanosize gold catalysts have superior catalytic behaviors, such as high catalytic activity, high catalytic stability and high resistance to moisture, and show a continuously increasing and more extensive application prospects. In this review, the preparation factors such as preparation method, support, particle size, pretreatment condition were summarized. The activation and reaction mechanisms were discussed.
Keywords:supported gold catalysts  CO oxidation  preparation methods  support effects  nanoparticles
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