| pH/温度响应的两亲性嵌段共聚物的研究 |
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| 引用本文： | 赵群,倪沛红.pH/温度响应的两亲性嵌段共聚物的研究[J].化学进展,2006,18(6):768-779. |
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| 作者姓名： | 赵群 倪沛红 |
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| 作者单位： | 苏州大学化学化工学院,江苏省有机合成重点实验室(苏州大学),苏州,215123 |
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| 基金项目： | 中国科学院资助项目;教育部重点实验室基金 |
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| 摘 要： | 刺激响应性两亲性嵌段共聚物由于具有多种潜在的用途而引起广泛关注。其中，pH和温度响应的嵌段共聚物被认为是较易获得并对外界环境刺激响应较敏感的一类聚合物。本文综述了利用各种可控/活性聚合方法制备不同结构刺激响应性的两亲性嵌段共聚物研究的最新进展，重点介绍聚（甲基）丙烯酸及其酯类与聚环氧乙烷(PEO)和聚环氧丙烷(PPO)类结构的两亲性嵌段共聚物的合成以及它们在水溶液中对pH值和温度变化的响应性。
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| 关 键 词： | null |
| 文章编号： | 1005-281X（2006）06-0768-12 |
| 收稿时间： | 2005-06-01 |
| 修稿时间： | 2005-11-01 |
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| Zhao Qun,Ni Peihong.null[J].Progress in Chemistry,2006,18(6):768-779. |
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| Authors: | Zhao Qun Ni Peihong |
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| Institution: | School of Chemistry and Chemical Engineering, Soochow University, The Key Laboratory of Organic Synthesis of Jiangsu Province, Suzhou 215123, China |
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| Abstract: | The stimuli-responsive amphiphilic block copolymers have drawn much attention due to their various promising potential applications.The pH and temperature responsive block copolymers are considerably important because they are relatively convenient to be synthesized and sensitive to outer stimuli.This review focuses on recent progress in stimuli-responsive and amphiphilic block copolymers containing polymethacrylates,poly(ethylene oxide)(PEO),and poly(propylene oxide)(PPO),which are prepared by various controlled/living polymerizations.The pH/temperature-responsive properties of these copolymers in aqueous solution are also summarized. |
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| Keywords: | pH/temperature-response amphiphilic block copolymers controlled/living polymerization polymethacrylates PEO PPO |
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