| 新型后过渡金属烯烃聚合催化剂－－镍系烯烃聚合催化剂* |
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| 引用本文： | 沈昊宇,金国新.新型后过渡金属烯烃聚合催化剂－－镍系烯烃聚合催化剂*[J].化学进展,2003,15(1):60. |
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| 作者姓名： | 沈昊宇 金国新 |
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| 作者单位： | (复旦大学化学系 上海 200433) |
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| 基金项目： | 国家自然科学基金 ( 2 99740 2 9,2 992 5 10 1)，国家重点基础研究专项经费 ( G19990 64 80 0 )资助项目 |
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| 摘 要： | 镍系烯烃聚合催化剂是近年来受到广泛关注的一类新型催化剂，是配位催化研究的热点之一。这类催化剂具有高催化活性、单活性中心和良好的分子剪栽性，可以在分子层次上实现烯烃聚合的分子设计与组装。本文介绍了镍系烯烃聚合催化剂的发展和研究概况，并评述了聚合特性及最新研究进展。
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| 关 键 词： | 镍系催化剂 后过滤金属催化剂 烯烃聚合反应 |
| 收稿时间： | 2001-12-01 |
| 修稿时间： | 2002-02-01 |
New Type Late Transition Metal Catalysts for Olefin Polymerization--Nickel-based Olefin Polymerization Catalysts |
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| Shen Haoyu,Jin Guoxin.New Type Late Transition Metal Catalysts for Olefin Polymerization--Nickel-based Olefin Polymerization Catalysts[J].Progress in Chemistry,2003,15(1):60. |
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| Authors: | Shen Haoyu Jin Guoxin |
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| Institution: | (Department of Chemistry,Fudan University, Shanghai 200433, China) |
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| Abstract: | Nickel-based olefin polymerization catalysts are new-type catalysts, which have been attracted much attention in recent years. Nickel-based catalysts possess high catalytic activity for olefin polymerization, with single active center and wonderful molecular tailoring properties.In the present review, the discovery, development, the polymerization characteristics and the most significant studies on the nickel-based olefin polymerization catalysts are reported. |
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| Keywords: | nickel-based catalysts late transition metal catalysts olefin polymerization |
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