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钯催化卤代芳烃的胺化反应研究
引用本文:刘蒲,李三华,李利民,王向宇,殷元骐,张玉华.钯催化卤代芳烃的胺化反应研究[J].化学进展,2005,17(2):0-292.
作者姓名:刘蒲  李三华  李利民  王向宇  殷元骐  张玉华
作者单位:1. 郑州大学化学系,郑州,450052
2. 中国科学院兰州化学物理研究所,兰州,730000
摘    要:钯催化卤代芳烃胺化是形成Car-N的重要方法.配体的发展扩展了底物的适用范围, 提高了反应的选择性,实现了廉价易得的氯代芳烃的胺化,弱碱的使用提高了官能团的兼 容性,因此Pd催化芳胺化广泛应用于合成芳胺类化合物.本文以卤代芳烃为线索,对钯催化偶联胺化反应的研究进展进行了综述和展望.

关 键 词:卤代芳烃    催化  胺化  偶联
文章编号:1005-281X(2005)02-0286-07
收稿时间:2003-12-01
修稿时间:2003年12月1日

Progress in Palladium-Catalyzed Amination of Aryl Halides
Liu Pu,Li Sanhua,Li Limin,Wang Xiangyu,Yin Yuanqi,Zhang Yuhua.Progress in Palladium-Catalyzed Amination of Aryl Halides[J].Progress in Chemistry,2005,17(2):0-292.
Authors:Liu Pu  Li Sanhua  Li Limin  Wang Xiangyu  Yin Yuanqi  Zhang Yuhua
Institution:1.Department of Chemistry, Zhengzhou University,Zhengzhou 450052,China; 2.Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences,Lanzhou 73000,China
Abstract:It is an important method to form CAr-N by palladium-catalyzed amination of aryl halides. The develop-ment of ligands expands the scope of substrates, improves reaction selectivity and realizes the amination of the cheaper and available aryl chlorides. The application of weak base improves the compatibility of functional groups. Pd-catalyzed amination of aryl halides are used in the synthesis of arylamine. The research progress in palladium-catalyzed amination is reviewed and prospected by using aryl halides as clue.
Keywords:aryl halides  palladium  catalysis  amination  cross-coupling
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