| 苯直接羟基化制苯酚研究进展* |
| |
| 引用本文： | 任永利,王莅,张香文.苯直接羟基化制苯酚研究进展*[J].化学进展,2003,15(5):420-426. |
| |
| 作者姓名： | 任永利 王莅 张香文 |
| |
| 作者单位： | （天津大学化工学院 天津 300072） |
| |
| 基金项目： | 973项目资助 (G2 0 0 0 0 4 80 0 5 ) |
| |
| 摘 要： | 综述了苯直接羟基化制苯酚的几种催化反应,包括阳极氧化法、N2O氧化法、H2O2氧化法、O2直接氧化法,这些反应均具有良好的原子经济性和环境效益.同时重点介绍了相关的催化剂及其活性中心,探讨了这些新型方法的工业应用前景.
|
| 关 键 词： | 苯羟基化 苯酚 阳极 一氧化二氮 过氧化氢 氧气 催化剂 |
| 文章编号： | 1005-281X(2003)05-0420-07 |
| 收稿时间： | 2002-06-01 |
| 修稿时间： | 2002年6月1日 |
Direct Hydroxylation of Benzene into Phenol |
| |
| Ren Yongli,Wang Li,Zhang Xiangwen.Direct Hydroxylation of Benzene into Phenol[J].Progress in Chemistry,2003,15(5):420-426. |
| |
| Authors: | Ren Yongli Wang Li Zhang Xiangwen |
| |
| Institution: | (School of Chemical Engineering, Tianjin University, Tianjin 300072, China) |
| |
| Abstract: | Recent progress of catalytic reactions for direct hydroxylation of benzene to phenol were reviewed, including anodic oxidation and catalytic oxidation with nitrous oxide, hydrogen peroxide or molecular oxygen. As oxidants all the reactions are environmentally friendly with high atomic economy. The relevant catalysts and active sites as well as the industrialization prospect of these reactions are also discussed. |
| |
| Keywords: | benzene hydroxylation phenol anode nitrous oxide hydrogen peroxide molecular oxygen catalyst |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
| 点击此处可从《化学进展》浏览原始摘要信息 |
| 点击此处可从《化学进展》下载免费的PDF全文 |
