| 功能化MCM-41在有机合成中的应用 |
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| 引用本文： | 赵东敏,赵继全,赵姗姗.功能化MCM-41在有机合成中的应用[J].化学进展,2007,19(4):510-519. |
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| 作者姓名： | 赵东敏 赵继全 赵姗姗 |
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| 作者单位： | 河北工业大学化工学院 天津 300130 |
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| 摘 要： | 介孔分子筛MCM-41具有较高的比表面和规整的结构以及表面带有羟基，因此可对MCM-41进行官能团化，从而实现均相催化剂在MCM-41中的组装，达到均相催化剂多相化的目的。本文介绍了最近几年以MCM-41为主体，组装均相配合物得到固相化催化剂在氧化、还原、烷基化、氢甲酰化、Heck、环丙烷化等反应中的应用。
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| 关 键 词： | MCM-41 固相化 氧化 还原 烷基化 氢甲酰化 Heck 环丙烷化 |
| 文章编号： | 1005-281X（2007）04-0510-10 |
| 收稿时间： | 2006-05 |
| 修稿时间： | 2006-07 |
Application of Functionalized MCM-41 in Organic Synthesis |
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| Zhao Dongmin,Zhao Jiquan,Zhao Shanshan.Application of Functionalized MCM-41 in Organic Synthesis[J].Progress in Chemistry,2007,19(4):510-519. |
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| Authors: | Zhao Dongmin Zhao Jiquan Zhao Shanshan |
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| Institution: | School of Chemical Engineering, Hebei University of Technology ,Tianjin 300130, China |
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| Abstract: | Mesoporous molecular sieves MCM-41 has large surface, ordered structure and silanol groups on its surface. It can be functionalized and applied to assembly homogeneous catalysis, which makes it possible to heterogenize homogeneous catalysts. Here we give a review about MCM-41 as host to assembly homogeneous complexes to get heterogenized catalysts and their applications in oxidation, reduction, alkylation, hydroformylation, Heck, cyclopropanation in recent years. |
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| Keywords: | MCM-41 heterogenization oxidation reduction alkylation hydroformylation Heck cyclopr-opanation |
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