| 环境友好催化氧化研究进展 |
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| 引用本文： | 童金辉,李臻,夏春谷.环境友好催化氧化研究进展[J].化学进展,2005,17(1):0-110. |
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| 作者姓名： | 童金辉 李臻 夏春谷 |
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| 作者单位： | 中国科学院兰州化学物理研究所,羰基合成与选择氧化国家重点实验室,兰州,730000;中国科学院兰州化学物理研究所,羰基合成与选择氧化国家重点实验室,兰州,730000;中国科学院兰州化学物理研究所,羰基合成与选择氧化国家重点实验室,兰州,730000 |
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| 基金项目： | 国家自然科学基金面上项目 (No.2 0 3730 82 ) |
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| 摘 要： | 综述了近来使用H2O2或O2作为清洁的氧化剂催化氧化反应的研究进展,重点介绍了杂多酸盐催化剂、金属配合物催化剂及NHPI等催化剂的组成和催化效率,并探讨了各种催化剂的优缺点.
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| 关 键 词： | 催化氧化 分子氧活化 H2O2 |
| 文章编号： | 1005-281X(2005)01-0096-15 |
| 收稿时间： | 2003-11-01 |
| 修稿时间： | 2004-03-01 |
Review on Environmentlly Friendly Catalytic Oxidation System |
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| Tong Jinhui,Li Zhen,Xia Chungu.Review on Environmentlly Friendly Catalytic Oxidation System[J].Progress in Chemistry,2005,17(1):0-110. |
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| Authors: | Tong Jinhui Li Zhen Xia Chungu |
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| Institution: | State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences,Lanzhou 73000,China |
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| Abstract: | Recent developments on catalytic oxidation systems are reviewed, in which hydrogen peroxide or molecular oxygen is used as clean oxidant. Many different kinds of catalysts including polyoxometalates, metal complex, NHPI and other catalysts are summarized. The focus is especially on their constitutes and catalytic efficiency. Advantages and disadvantages of each kind of catalytic system are also discussed. |
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| Keywords: | catalytic oxidation dioxygen activation hydrogen peroxide |
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