An Approach to Paracyclophane-Based Tetrathiafulvalenes: Synthesis and Characterization of a Pseudo-Geminal [2.2]Paracyclophane 1,3-Dithia-2-Thione |
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| Authors: | Lucian G Bahrin Henning Hopf Peter G Jones Mihail L Birsa Laura G Sarbu |
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| Institution: | 1.Petru Poni Institute of Macromolecular Chemistry, Intelcenter. 41A Grigore Ghica Vodă Alley, 700487 Iasi, Romania; ;2.Institute of Organic Chemistry, Technical University of Braunschweig, Hagenring 30, D-38106 Braunschweig, Germany; ;3.Institute of Inorganic and Analytical Chemistry, Technical University of Braunschweig, Hagenring 30, D-38106 Braunschweig, Germany; ;4.Department of Chemistry, Alexandru Ioan Cuza University of Iasi, 11 Carol I Blvd., 700506 Iasi, Romania |
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| Abstract: | The synthesis of paracyclophane-based tetrathiafulvalene precursors is described in the context of the importance of these compounds in the field of material chemistry. Pseudo-geminal bis(1,3-dithia-2-thione) was synthesized via the corresponding 1,3-dithiol-2-ylium salt. The latter was obtained by a synthetic procedure that involves 4,15-bis(acetyl)2.2]paracyclophane, a new compound of interest for many researchers. |
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| Keywords: | [2 2]paracyclophanes dithiocarbamates 1 3-dithiolium salts trithiones |
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