The synthesis of mesoporous zeolite beta aggregates without the use of second template and additive |
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| Authors: | Shu-Ping Liu Li Chen Yi Meng Wang |
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| Institution: | Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Chemistry Department, East China Normal University, North Zhongshan Road 3663, Shanghai 200062, PR China |
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| Abstract: | Zeolite Beta Aggregates have been synthesized by the self-assembly of Beta nanoparticles without the use of second template or additive, where the large zeolitic aggregates avoided the filtration difficulties and the presence of mesopore reduced the diffusion limitation. The samples were characterized by XRD, N2-sorption, SEM, TEM, thermogravimetric analysis, IR spectroscopy and temperature programmed desorption of ammonia. The results showed that the SiO2/Al2O3 ratio played a key role on the particle size, mesopore volume and particle–particle aggregation process of zeolite Beta. The sample with SiO2/Al2O3 ratio below 60 had improved textual and acidic properties and exhibited the best catalytic activity to the alkylation of phenol with tert-butanol. |
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