Hydrothermal Synthesis of the Blue Potassium Molybdenum Bronze, K<sub>0.28</sub>MoO<sub>3</sub>期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

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Hydrothermal Synthesis of the Blue Potassium Molybdenum Bronze, K_0.28MoO₃

Authors:	Kin ChinKazuo Eda Noriyuki Sotani MStanley Whittingham

Institution:	^a Department of Chemistry, Faculty of Science, Kobe University, Nada-ku, Kobe, 657-8501, Japan ^b Institute for Materials Research, State University of New York at Binghamton, Binghamton, New York, 13902-6000

Abstract:	Blue potassium molybdenum bronze, K_0.28MoO₃, was prepared by hydrothermal heating hydrogen molybdenum bronze in KCl solution at 431 K. Hydrated molybdenum bronze was found formed as an intermediate during the conversion from hydrogen molybdenum bronze to blue bronze. The hydrothermal method proved itself an easy and effective for synthesis of mixed-valence compounds.

Keywords:	hydrothermal reaction blue bronze alkali metal molybdenum bronze low-temperature synthesis route hydrated molybdenum bronze hydrogen molybdenum bronze mixedvalence compound topotactical reaction
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