Physicochemical properties of alkali metal cation-TCNQ anion radical salts |
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Authors: | Ichimin Shirotani Nobuko Sakai |
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Institution: | The Institute for Solid State Physics, The University of Tokyo, Roppongi, Minato-ku, Tokyo 106 Japan |
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Abstract: | Simple alkali metal cation-TCNQ anion radical salts are classified in two groups from the differences in their physicochemical properties and crystal structures. Li-, Na-, K-, and Rb(I)-TCNQ are comprised in Group A. Li-TCNQ exhibits distinct behavior from other salts in Group A. Rb(II)- and Cs-TCNQ belong to Group B. Phase transitions, electrical conductivities, and absorption spectra in these simple salts are closely related to their crystal structures. |
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