Solvothermal syntheses of Cu3P via reactions of amorphous red phosphorus with a variety of copper sources |
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| Authors: | Jennifer Ann Aitken Stephanie L Brock |
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| Institution: | a Department of Chemistry and Biochemistry, Duquesne University, Pittsburgh, PA 15282, USA
b Department of Chemistry, Wayne State University, 5101 Cass Avenue, Detroit, MI 48202-3929, USA |
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| Abstract: | Polycrystalline Cu3P was successfully prepared under a wide variety of solvothermal conditions. The reaction of red phosphorus with several copper sources (copper metal, copper (I) iodide, copper (I) chloride and copper (II) chloride) at 150-200 °C for 1-2 days in water produced Cu3P. Products were examined with powder X-ray diffraction, scanning electron microscopy and energy dispersive spectroscopy. Thermal analyses and optical spectroscopy were also performed. A detailed list of reaction conditions, products and impurity phases (where applicable) are reported. |
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| Keywords: | Solvothermal Hydrothermal Copper phosphide Transition metal phosphide Phosphide Pnictide Low temperature synthesis Microcrystalline |
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