Ortho C–H arylation of arenes at room temperature using visible light ruthenium C–H activation |
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| Authors: | Arunachalam Sagadevan Anastasios Charitou Fen Wang Maria Ivanova Martin Vuagnat Michael F Greaney |
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| Institution: | School of Chemistry, The University of Manchester, Oxford Road, Manchester M13 9PL UK, |
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| Abstract: | A ruthenium-catalyzed ortho C–H arylation process is described using visible light. Using the readily available catalyst RuCl2(p-cymene)]2, visible light irradiation was found to enable arylation of 2-aryl-pyridines at room temperature for a range of aryl bromides and iodides.A ruthenium-catalyzed ortho C–H arylation process is described using visible light. |
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