Wave packet driven dissociation and concerted elimination in CH2I2 |
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Authors: | Geissler Dominik Pearson Brett J Weinacht Thomas |
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Institution: | Department of Physics, Stony Brook University, Stony Brook, NY 11794, USA. |
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Abstract: | We follow the evolution of a vibrational wave packet in a highly excited state of the halogenated methane CH(2)I(2). We observe how the wave packet modulates both dissociation and concerted elimination to form CH(2)I(+) and I(2) (+), respectively. We present a simple and intuitive interpretation of the molecular dynamics leading to the formation of the products. |
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