| 2,4,6-三对氨基苯氧基-1,3,5-均三嗪的合成 |
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| 引用本文： | 陈剑伟,王晓琴,罗翠娥,郑雪琳,翁家宝.2,4,6-三对氨基苯氧基-1,3,5-均三嗪的合成[J].广州化学,2010,35(1):33-37. |
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| 作者姓名： | 陈剑伟 王晓琴 罗翠娥 郑雪琳 翁家宝 |
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| 作者单位： | 1. 福建师范大学化学与材料学院,福建,福州,350007
2. 福建师范大学化学与材料学院;福建师范大学福建省高分子材料重点实验室,福建,福州,350007 |
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| 基金项目： | 国家自然科学基金资助项目(20874012) |
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| 摘 要： | 以三聚氯氰和对硝基苯酚为原料,经取代、还原合成了2,4,6-三对氨基苯氧基-1,3,5-均三嗪。对Pd/C水合肼、SnCl2·2H2O-HCl及Pd/C催化加氢三种不同还原体系进行比较。采用1H-NMR、FT-IR和元素分析方法对产物进行结构表征。
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| 关 键 词： | 三聚氯氰 树枝状大分子 硝基还原 Pd/C催化 合成 |
Synthesis of 2,4,6-Tris(4-Aminophenoxy)-1,3,5-Triazine |
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| CHEN Jian-wei,WANG Xiao-qin,LUO Cui-e,ZHEN Xue-lin,WENG Jia-bao.Synthesis of 2,4,6-Tris(4-Aminophenoxy)-1,3,5-Triazine[J].Guangzhou Chemistry,2010,35(1):33-37. |
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| Authors: | CHEN Jian-wei WANG Xiao-qin LUO Cui-e ZHEN Xue-lin WENG Jia-bao |
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| Institution: | 1. College of Chemistry and Materials Science;Fujian Normal University;2. Key Laboratory of Polymer Materials of Fujian Province;Fuzhou 350007;China |
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| Abstract: | 2,4,6-Tris(4-nitrophenoxy)-1,3,5-triazine, which was synthesized by nucleophilic substitution reaction of cyanuric chloride with p-nitrophenol. And three different reduction systems were used: hydrazine hydrate, stannous chloride and catalytic hydrogenation in order to get 2,4,6-tris(4-aminophenoxy)-1,3,5-triazine. The products were characterized by 1H-NMR, FT-IR and elemental analysis. |
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| Keywords: | cyanuric chloride dendrimer reduction Pd/C catalytic systhesis |
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