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| 微波辐射法合成4-氨基邻苯二甲酰亚胺 | |
| 引用本文： | 张亚男,唐有根,肖方明.微波辐射法合成4-氨基邻苯二甲酰亚胺[J].广州化学,2010,35(2):43-47. |
| 作者姓名： | 张亚男 唐有根 肖方明 |
| 作者单位： | 1. 中南大学,化学化工学院,湖南,长沙,410083;广州有色金属研究院,稀有金属研究所,广东,广州,510651 2. 中南大学,化学化工学院,湖南,长沙,410083 3. 广州有色金属研究院,稀有金属研究所,广东,广州,510651 |
| 摘 要： | 以4-硝基邻苯二甲酰亚胺为原料,通过微波辐射合成了4-氨基邻苯二甲酰亚胺。结果表明:选择铁粉作为催化剂,乙酸乙酯为萃取剂,在4-硝基邻苯二甲酰亚胺/氯化铵/铁粉的摩尔比为1.0∶1.0∶3.5,微波辐射时间100 s,微波辐射功率480 W的条件下,4-氨基邻苯二甲酰亚胺的收率最高,达到93.4%。 |
| 关 键 词： | 4-氨基邻苯二甲酰亚胺 4-硝基邻苯二甲酰亚胺 微波辐射 |
Study of Synthesizing 4-aminophthalimide Under Microwave Radiation |
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| ZHANG Ya-nan,TANG You-gen,XIAO Fang-ming.Study of Synthesizing 4-aminophthalimide Under Microwave Radiation[J].Guangzhou Chemistry,2010,35(2):43-47. | |
| Authors: | ZHANG Ya-nan TANG You-gen XIAO Fang-ming |
| Institution: | 1. College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China; 2. Guangzhou Research Institute of Non-Metals, Guangzhou 510651, China) |
| Abstract: | The 4-aminophthalimide has been synthesized from 4-nitrophthalimide by microwave irradiation. The result showed that the yield of the product was 93.4% under the optimum reaction conditions as follows： Fe powder was catalyst. DMF was extracting agent. Molar ration of 4-nitrophthalimide, ammonium chloride and Fe powder was 1 ： 1.08 ： 3.6. Microwave time was 100 s. Microwave power was 480 W. |
| Keywords: | 4-aminophthalimide 4-nitrophthalimide microwave |
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