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A new rhodium complex with a nitrogen‐containing bis(phosphine oxide) ligand as an efficient catalyst for the hydroformylation of styrene |
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| Authors: | Evangelos I Tolis Kalliopi A Vallianatou Fotini J Andreadaki Ioannis D Kostas |
| Abstract: | A new rhodium complex with a nitrogen‐containing bis(phosphine oxide) ligand has been synthesized. The complex was applied to hydroformylation of styrene and displayed high activity and regioselectivity towards the branched aldehyde, which was found to be higher than those of the tertiary bis(phosphine) analogue. Copyright © 2006 John Wiley & Sons, Ltd. |
| Keywords: | amino phosphine oxide bis(phosphine oxide) hemilabile ligand rhodium complex hydroformylation homogeneous catalysis |