Equilibrium and kinetic study of novel methyltrimethoxysilane magnetic titanium dioxide nanocomposite for methylene blue adsorption from aqueous media |
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| Authors: | Parvin Alizadeh Eslami Mohammad Afzal Kamboh Hamid Rashidi Nodeh Wan Aini Wan Ibrahim |
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| Institution: | 1. Department of Chemistry, Faculty of Science, Tabriz Branch, Islamic Azad University, Tabriz, Iran;2. Department of Chemistry, Shaheed Benazir Bhutto University, Shaheed Benazirabad, Sindh, Pakistan;3. Young Researchers and Elite Club, Science and Research Branch, Islamic Azad University, Tehran, Iran;4. Department of Chemistry, Faculty of Science, Universiti Teknologi Malaysia, Johor Bahru, Johor, Malaysia;5. Centre for Sustainable Nanomaterials, Ibnu Sina Institute for Scientific and Industrial Research, Universiti Teknologi Malaysia, Johor Bahru, Johor, Malaysia |
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| Abstract: | Novel magnetic titanium dioxide nanoparticles decorated with methyltrimethoxysilane (Fe3O4@TiO2‐MTMOS) were successfully fabricated via a sol–gel method at room temperature. The synthesized material was characterized using Fourier transform infrared spectroscopy, X‐ray diffraction, scanning electron microscopy, energy‐dispersive X‐ray spectroscopy, thermogravimetric analysis and vibrating sample magnetometry. The removal efficiency of the adsorbent was evaluated through the adsorption of methylene blue (MB) dye from water samples. The adsorption isotherm and kinetics were evaluated using various models. The Langmuir model indicated a high adsorption capacity (11.5 mg g?1) of Fe3O4@TiO2‐MTMOS. The nanocomposite exhibited high removal efficiency (96%) and good regeneration (10 times) compared to Fe3O4 and Fe3O4@TiO2 at pH = 9.0. Based on the adsorption mechanism, electrostatic interaction plays a main role in adsorption since MB dye is cationic in nature at pH = 9, whereas the adsorbent acquired an anionic nature. The newly synthesized Fe3O4@TiO2‐MTMOS can be used as a promising material for efficient removal of MB dye from aqueous media. |
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| Keywords: | adsorption isotherm and kinetics Fe3O4@TiO2 nanoparticles Fe3O4@TiO2– methyltrimethoxysilane nanocomposite methylene blue dye |
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